彭谦
彭谦
博士 研究员
彭谦,博士,研究员,元素有机化学研究所,毕业于中科院上海有机所,河南郑州人。
工作内容:教学科研
特殊人才称号:国家“四青”人才,欧盟玛丽居里学者,天津市杰出青年
通讯地址:天津市卫津路94号南开大学化学楼中楼708室

电 话:(+86) 022 23502080

电子邮件:qpeng@nankai.edu.cn

课题组网站:
研究领域:理论有机化学,计算化学,分子波谱模拟
教育及科研经历:

2000-2004 中山大学 本科 理学学士

2004-2009 中国科学院上海有机所 博士(师从吴云东院士) 理学博士

2009-2010 中国科学院上海有机所 助理研究员

2010-2013 美国University of Notre Dame 博士后 

2013-2014 美国Texas A&M University 高级研究学者 

2014-2016 英国Univeristy of Oxford 玛丽居里研究员

2017-至今 南开大学化学学院 特聘研究员

荣誉和奖励

2020年 Thieme Chemistry Journals Award

2019年 天津市杰出青年基金

2019年 获国家自然科学基金重大项目课题资助

2017年 获国家和天津市引进人才

2016年 “Chemical Structure Association(CSA) Trust ”基金奖

2016年 “Nature Chemistry”口头报告奖和“Org. Chem. Front. ”口头报告奖

2014年 欧盟玛丽居里奖金(FP7-PEOPLE-IIF Marie Curie Fellowship)

2014年 国家自然科学二等奖 (第五)

2013年 上海市自然科学一等奖(第五)

2009年 中国科学院三好学生

2004年 中山大学优秀毕业生

科研成果与代表作

目前已经在Chem.Soc.Rev.(1篇), Acc. Chem. Res.(1篇), Nature.Commun.(5篇),J. Am. Chem. Soc.(9篇),Angew. Chem. Int. Ed.(11篇),Chem. Sci.(2 篇), ACS Central Science(1篇),ACS Catalysis(4 篇), 等国际权威期刊发表学术论文50余篇.


研究论文:

1.Bin Lu, Xinyi Liang, Jinyu Zhang, Zijian Wang, Qian Peng,* and Xiaoming Wang*, Dirhodium(II)/ Xantphos Catalyzed Relay Carbene Insertion and Allylic Alkylation Process: Reaction Development and Mechanistic Insights. J. Am. Chem. Soc., 2021,11799-11810.

2.Jie Dong#, Hong-De An#, Ze-Kun Yue#, Sheng-Li Hou, Yao Chen*, Zhen-Jie Zhang, Peng Cheng, Qian Peng*, Bin Zhao*,Dual-Selective Catalysis in Dephosphorylation Tuned by Hf6-Containing MetalOrganic Frameworks Mimicking Phosphatase, ACS Central Science, 2021, 7, 831-840.

3.Huan Zhang#; Enhui Wang#; Shasha Geng; Zhengli Liu; Yun He; Qian Peng*; Zhang Feng*; Experimental and Computational Studies on the Iron‐Catalyzed Selective and Controllable Defluorosilylation of Unactivated Aliphatic gem-Difluoroalkenes, Angew. Chem. Int. Ed., 2021, 60, 10211-10218.

4.Xia Zhong; Ziwei Zhong; Zhikun Wu; Zhen Ye; Yuxiang Feng; Shunxi Dong; Xiaohua Liu*; Qian Peng*; Xiaoming Feng*; Chiral Lewis acid-bonded picolinaldehyde enables enantiodivergent carbonyl catalysis in the Mannich/condensation reaction of glycine ester, Chemical Science, 2021, 12, 4353-4360.

5.Cheng Xu, # Zhen Ye, # Li Xiang, Shuhan Yang, Qian Peng,* Xuebing Leng, Yaofeng Chen* Insertion of Metal-substituted Silylene into Naphthalene’s Aromatic Ring and Subsequent Rearrangement for Silaspiro-benzocycloheptenyl and Cyclobutenosilaindan Derivatives. Angew. Chem. Int. Ed.  2021, 60, 3189-3195. 

6.Jiawen Wang,# Sujuan Zheng,# Subramani Rajkumar, Jinglei Xie, Na Yu, Qian Peng,* Xiaoyu Yang* Chiral phosphoric acid catalyzed stereodivergent synthesis of trisubstituted allenes and computational mechanistic studies. Nature Communication 2020, 11,5527.

7.Lei Kang,# Yongjia Lin,# Zeng Gao, Jinlong Zhang, Huameng Yang, Jinlong Qian,* Qian Peng,* Gaoxi Jiang*, Fluorine Effect for Tuning C-C and C-S Bond Cleavage in Fluoro-Julia-Kocienski Intermediates, CCS Chem, 2020, 2, 1678-1689.

8.Tao Zhang, Yu-Xin Luan, Su-Juan Zheng, Qian Peng*, Mengchun Ye* Chiral Aluminum-Controlled Ni-catalyzed Enantioselective Synthesis of Indenes via C-CN Bond Activation. Angew. Chem. Int. Ed.  2020, 59, 7439 –7443.

9.Bo Zhou, Ying-Qi Zhang, Kairui Zhang, Yang-Bo Chen, You Li, Qian Peng,* Shou-Fei Zhu,* Qi-Lin Zhou,and Long-Wu Ye*,Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement. Nature Communication 2019.10,3234.

10.Guangzhu Wang#, Xinyi Liang#, Lili Chen, Qian Gao, Jian-Guo Wang, Panke Zhang,* Qian Peng,* and Senmiao Xu*, Iridium-Catalyzed Distal Hydroboration of Aliphatic Internal Alkenes. Angew. Chem. Int. Ed.  2019, 58, 8187-8191.

11.Jianping Zhao#, Qian Peng#,Zijian Wang, Wei Xu, Hongyan Xiao, Qi Wu, Hao-Ling Sun, Fang Ma,Jiyong Zhao, Cheng-Jun Sun, Jianzhang Zhao, and Jianfeng Li*, Proton mediated spin state transition of cobalt heme analogues, Nature Communication 2019. 10, 2303.

12.Xian-Shuang Tu, Ning-Ning Zeng, Ru-Ye Li, Yu-Quan Zhao, De-Zhen Xie, Qian Peng* and Xiao-Chen Wang*. C2-Symmetric Bicyclic Bis-Borane Catalysts: Kinetic or Thermodynamic Products from a Reversible Hydroboration of Dienes. Angew. Chem. Int. Ed.  2018, 57, 15096-15100.

13.Fengmin Guo, Zekun Yue, Marko Trajkovski, Xiaoping Zhou, Dong Cao, Qiang Li, Baifan Wang, Xin Wen, Janez Plavec*, Qian Peng*, Zhen Xi, and Chuanzheng Zhou*.Effect of Ribose Conformation on RNA Cleavage via Internal Transesterification. J. Am. Chem. Soc. 2018, 140, 11893-11897.

14.Subramani Rajkumar#, Jiawen Wang#, Sujuan Zheng, Donglei Wang, Xueqian Ye, Xuejiao Li, Qian Peng*, Xiaoyu Yang*, Regioselective and enantioselective synthesis of β-indolyl cyclopentenamides through chiral anion catalysis. Angew. Chem. Int. Ed.  2018, 57,13489 –13494.

15.Hao Wang, Zibo Bai, Tangqian Jiao, Zhiqiang Deng, Huarong Tong, Gang He*, Qian Peng*, and Gong Chen*.Palladium-Catalyzed Amide-Directed Enantioselective Hydrocarbo-functionalization of Unactivated Alkenes Using a Chiral Monodentate Oxazoline Ligand. J. Am. Chem. Soc. 2018,  140, 3542-3546.

16.Qian Peng*, Zengwei Wang, Snezana D. Zaric, Edward N. Brothers, and Michael B. Hall*.Unraveling the Role of a Flexible Tetradentate Ligand in the Aerobic Oxidative Carbon-Carbon Bond Formation with Palladium Complexes: A Computational Mechanistic Study. J. Am. Chem. Soc. 2018, 140, 3929-3939.

17.Meng-Yang Hu, Qiao He, Song-Jie Fan, Zi-Chen Wang, Luo-Yan Liu, Yi-Jiang Mu, Qian Peng* and Shou-Fei Zhu*,Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation. Nature Communication 2018. 9, 221.

18.Arghya Deb, Avijit Hazra, Qian Peng*, Robert S. Paton*, Debabrata Maiti*, Detailed Mechanistic Studies on Palladium Catalyzed Stereoselective C–H Olefination with Aliphatic Alkenes: A Significant Influence of Proton Shuttling. J. Am. Chem. Soc. 2017, 136, 763-775. 

19.Robert Strack, Qian Peng*, Aroonroj Mekareeya‎, Robert.Paton* and Edward Anderson*, Computational Ligand Design in Enantio- and Diastereoselective Ynamide [5+2] Cycloisomerization, Nature Communication 2016. 7:10109.


综述文章

1.Qian Peng#, Fernanda Duarte#, Robert S. Paton, Computing Organic Stereoselectivity – from Concepts to Quantitative Calculations and Predictions, Chem. Soc. Rev., 2016, 45, 6093-6107.

2.Qian Peng*, Robert S. Paton*, Catalytic Control in Cyclizations: from Computational Mechanistic Understanding to Selectivity Prediction. Acc. Chem. Res. 2016 49, 1042-1051.

人才培养

在读硕士7名和博士6名,培养学生获国家奖学金,金发科技奖学金,万香奖学金。培养本科生获杨石先奖学金,并已获UC University of California, Berkeley,University of Minnesota著名课题组读研或交流机会。

课题组计划每年招收博士生2名,硕士生2名,接收校内外保送生,直博生。欢迎化学,物理,计算机等专业本科生、硕士、博士、博士后的加入。

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