张弛
张弛
博士 教授
张弛,博士,教授,元素有机化学研究所,毕业于香港大学,河南人。
工作内容:教学科研
人才称号:新世纪优秀人才支持计划入选者
通讯地址:天津市卫津路94号南开大学元素所316室
电 话:
电子邮件:zhangchi@nankai.edu.cn
课题组网站:http://skleoc.nankai.edu.cn/professors/zhangc/zhangchi.htm
研究领域:

有机合成化学,目前主要从事的研究领域:(1) 有机高价碘试剂(hypervalent iodine chemistry)新反应性的研究,设计合成新的有机高价碘试剂并探索它们的新反应性;(2)寡肽的合成;(3) C-H 键的官能团化;(4)有机氟化物的绿色合成(5)天然产物的全合成。

请详见http://skleoc.nankai.edu.cn/professors/zhangc/zhangchi.htm

教育及科研经历:

张弛,博士,教授,博士生导师。南开大学元素有机化学国家重点实验室固定研究人员。1990年本科毕业于兰州大学化学系,1993年考入兰州大学化学系,1996年获理学硕士学位,1996年底至2001年初在香港大学化学系攻读并获得博士学位。2001年至2003年在美国Stanford大学化学系做博士后,研究模拟酶。2003年任南开大学教授、2005年任博士生导师,2007年入选教育部新世纪优秀人才支持计划。

1990 B.S., Lanzhou University (兰州大学)

1996 M.Sc., Lanzhou University (兰州大学)

2001 Ph.D., The University of Hong Kong (香港大学)

2001-2003 Postdoctoral Fellow, Stanford University (斯坦福大学) 

2003年至今 Professor, College of Chemistry, Nankai University (南开大学)

2005年至今 博士生导师,南开大学

荣誉和奖励

2007年,教育部新世纪优秀人才

科研成果与代表作

1. “Practical Peptide Synthesis Mediated by a Recyclable Hypervalent Iodine Reagent and Tris(4-methoxyphenyl)phosphine” C. Zhang*, S.-S. Liu, B. Sun, J. Tian, Org. Lett. 2015, 17, 4106-4109.

2. “Recyclable Hypervalent-Iodine-Mediated Dehydrogenative α,β′-Bifunctionalization of β-Keto Esters Under Metal-Free Conditions” Y.-N. Duan, L.-Q. Cui, L.-H. Zuo, C. Zhang*, Chem. Eur. J. 2015, 21, 13052-13057.

3. “Iodosodilactone as a Recyclable Oxidant for Efficient Oxidation of Alcohols to Carbonyl Compounds” A. Song, C. Zhang*, Acta Chim. Sinica 2015, DOI: 10.6023/A15050355.

4. “Synthesis of Oxazolidin-2-ones and Imidazolidin-2-ones Directly from 1,3-Diols or 3-Amino Alcohols using Iodobenzene Dichloride and Sodium Azide” T. He, W.-C. Gao, W.-K. Wang, C. Zhang*, Adv. Synth. Catal. 2014, 356, 1113-1118.

5. “Boron Trifluoride Etherate Functioning as a Fluorine Source in an Iodosobenzene-Mediated Intramolecular Amino?uorination of Homoallylic Amines” J. Cui, Q. Jia, R.-Z. Feng, S.-S. Liu, T. He, C. Zhang*, Org. Lett. 2014, 16, 1442-1445.

6. “Iodine-Mediated Intramolecular Amination of Ketones: the Synthesis of 2-Acylindoles and 2-Acylindolines by

Tuning N-Protecting Groups” W.-C. Gao, S. Jiang, R.-L. Wang, C. Zhang*, Chem. Commun. 2013, 49, 4890-4892.

7. “Practical Oxazole Synthesis Mediated by Iodine from α-Bromoketones and Benzylamine Derivatives” W.-C. Gao, R.-L. Wang, C. Zhang*, Org. Biomol. Chem. 2013, 11, 7123-7128.

8. “Recyclable Hypervalent Iodine(III) Reagent Iodosodilactone as an Efficient Coupling Reagent for Direct Esterification, Amidation, and Peptide Coupling” J. Tian, W.-C. Gao, D.-M. Zhou, C. Zhang*, Org. Lett. 2012, 14, 3020-3023. 

9. “A Mild and Efficient Direct ?-Amination of ?-Dicarbonyl Compounds Using Iodosobenzene and p-Toluenesulfonamide Catalyzed by Perchlorate Zinc Hexahydrate” J. Yu, S.-S. Liu, J. Cui, X.-S. Hou, C. Zhang*, Org. Lett. 2012, 14, 832-835. 

10. “A Dramatic Solvent Effect on One-Pot Synthesis of Substituted Ureas Directly from Primary Alcohols Using the Combined Reagent of Iodobenzene Dichloride and Sodium Azide in Ethyl Acetate” C. Zhang*, W.-K. Wang, T. He, Synthesis 2012, 44, 3006-3014 (invited).

11. “Enantioselective ?-tosyloxylation of ketones catalyzed by spirobiindane scaffold-based chiral iodoarenes” J. Yu, J. Cui, X.-S. Hou, S.-S. Liu, W.-C. Gao, S. Jiang, J. Tian, C. Zhang*, Tetrahedron: Asymmetry. 2011, 22, 2039-2055.

12. “Design, Synthesis, Structure, and Dehydrogenation Reactivity of a Water-Soluble o-Iodoxybenzoic Acid Derivative Bearing a Trimethylammonium Group” L.-Q. Cui, Z.-L. Dong, K. Liu, C. Zhang*, Org. Lett. 2011, 13, 6488-6491.

13. “Effective oxidation of benzylic and alkane C–H bonds catalyzed by sodium o-iodobenzenesulfonate with Oxone as a terminal oxidant under phase-transfer conditions” L.-Q. Cui, K. Liu, C. Zhang*, Org. Biomol. Chem. 2011, 9, 2258-2265.

14. “One-Pot Synthesis of Symmetrical 1,3-Diarylureas or Substituted Benzamides Directly from Benzylic Primary Alcohols and Effective Oxidation of Secondary Alcohols to Ketones Using Phenyliodine Diacetate in Combination with Sodium Azide” X.-Q. Li, W.-K. Wang, Y.-X. Han, C. Zhang*, Adv. Synth. Catal. 2010, 352, 2588-2598.

15. “Various ?-Oxygen Functionalizations of ?-Dicarbonyl Compounds Mediated by the Hypervalent Iodine(III) Reagent p-Iodotoluene Difluoride with Different Oxygen-Containing Nucleophiles” J. Yu, J. Tian, C. Zhang*, Adv. Synth. Catal. 2010, 352, 531-546.

16. “One-Pot Synthesis of Carbamoyl Azides Directly from Primary Alcohols and Oxidation of Secondary Alcohols to Ketones Using Iodobenzene Dichloride in Combination with Sodium Azide” X.-Q. Li, W.-K. Wang, C. Zhang*, Adv. Synth. Catal. 2009, 351, 2342-2350.

17. “A Safe, Convenient and Efficient One-Pot Synthesis of ?-Chloroketone Acetals Directly from Ketones Using Iodobenzene Dichloride” J. Yu, C. Zhang*, Synthesis 2009, 2324-2328.

18. “An Environmentally Benign TEMPO-Catalyzed Efficient Alcohol Oxidation System with a Recyclable Hypervalent Iodine(III) Reagent and Its Facile Preparation” X.-Q. Li, C. Zhang*, Synthesis 2009, 1163-1169.

19. “Iodobenzene dichloride in combination with sodium azide for the effective synthesis of carbamoyl azides from aldehydes” X.-Q. Li, X.-F. Zhao, C. Zhang*, Synthesis 2008, 2589-2593.

20. “Iodobenzene dichloride as a stoichiometric oxidant For the conversion of alcohols into carbonyl compounds; Two facile methods for its preparation” X.-F. Zhao, C. Zhang*, Synthesis 2007, 551-557.

21. “A Simple and Effective Synthesis of Benzolactones and Benzolactams by Noncatalytic Benzylic Oxidation of Cyclic Benzylic Ethers and N-Protected Cyclic Benzylic Amines with Sodium Chlorite as an Oxidant” A.-R. Song, J. Yu, C. Zhang*, Synthesis 2012, 44, 2903-2909. 

22. “A Simple and Effective Method for ?-Hydroxylation of ?-Dicarbonyl Compounds Using Oxone as an Oxidant without a Catalyst” J. Yu, J. Cui, C. Zhang*, Eur. J. Org. Chem. 2010, 7020-7026.

23. “A Simple Method for Epoxidation of Olefins Using Sodium Chlorite as an Oxidant without a Catalyst” X.-L. Geng, Z. Wang, X.-Q. Li, C. Zhang*, J. Org. Chem. 2005, 70, 9610-9613.

人才培养

毕业:博士生7人,硕士生11人。

在读:博士生5人,硕士生6人。


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